8 research outputs found
Advanced reliability analysis of polymer electrolyte membrane fuel cells in automotive applications
Hydrogen fuel cells have the potential to dramatically reduce emissions from the energy sector,
particularly when integrated into an automotive application. However, there are three main
hurdles to the commercialisation of this promising technology; one of which is reliability. Cur-
rent standards require an automotive fuel cell to last around 5000 h of operation (equivalent
to around 150,000 miles), which has proven difficult to achieve to date. This hurdle can be
overcome through in-depth reliability analysis including techniques such as Failure Mode and
Effect Analysis (FMEA), Fault Tree Analysis (FTA) and Petri-net simulation. This research
has found that the reliability field regarding hydrogen fuel cells is still in its infancy, and needs
development, if the current standards are to be achieved. In this research, a detailed reliability
study of a Polymer Electrolyte Membrane Fuel Cell (PEMFC) is undertaken. The results of
which are a qualitative and quantitative analysis of a PEMFC. The FMEA and FTA are the
most up to date assessments of failure in fuel cells developed using a comprehensive literature
review and expert opinion.
Advanced modelling of fuel cell degradation logic was developed using Petri-net modelling
techniques. 20 failure modules were identfied that represented the interactions of all failure
modes and operational parameters in a PEMFC. Petri-net simulation was used to overcome key
pitfalls observed in FTA to provide a verfied degradation model of a PEMFC in an automotive
application, undergoing a specific drive cycle, however any drive cycle can be input to this
model. Overall results show that the modeled fuel cell's lifetime would reach 34 hours before
falling below the industry standard degradation rate of more than 5%. The degradation model
has the capability to simulate fuel cell degradation under any drive cycle and with any operating
parameters.
A fuel cell test rig was also developed that was used to verify the simulated degradation.
The rig is capable of testing single cells or stacks from 0-470W power. The results from the
verification experimentation agreed strongly with the degradation model, giving confidence in
the accuracy of the developed Petri-net degradation model.
This research contributes greatly to the field of reliability of PEMFCs through the most
up-to-date and comprehensive FMEA and FTA presented. Additionally, a degradation model
based upon Petri-nets is the first degradation model to encompass a 1D performance model to
predict fuel cell life time under specific drive cycles
Failure mode and effect analysis, and fault tree analysis of polymer electrolyte membrane fuel cells
Hydrogen fuel cells have the potential to dramatically reduce emissions from the energy sector, particularly when integrated into an automotive application. However there are three main hurdles to the commercialisation of this promising technology; one of which is reliability. Current standards require an automotive fuel cell to last around 5000 h of operation (equivalent to around 150,000 miles), which has proven difficult to achieve to date. This hurdle can be overcome through in-depth reliability analysis including techniques such as Failure Mode and Effect Analysis (FMEA) and Fault Tree Analysis (FTA) amongst others. Research has found that the reliability field regarding hydrogen fuel cells is still in its infancy, and needs development, if the current standards are to be achieved. In this work, a detailed reliability study of a Polymer Electrolyte Membrane Fuel Cell (PEMFC) is undertaken. The results of which are a qualitative and quantitative analysis of a PEMFC. The FMEA and FTA are the most up to date assessments of failure in fuel cells made using a comprehensive literature review and expert opinion
Enhanced Fault Tree analysis and modelling considerations of a Polymer Electrolyte Membrane Fuel Cell
With the recent increase in interest in environmental issues and climate change concerns, the scientific community have been tasked with developing low carbon technologies to mitigate against climate change. One of the most promising technologies is the hydrogen fuel cell, particularly when integrated into an automobile. Hydrogen Fuel Cells are an electro-chemical, zero-emission energy conversion and power generation device. Their only output products are heat, electrical energy, and water vapour.
There are three main hurdles to the commercial uptake of this technology; Infrastructure, Cost and Reliability. An understanding of the reliability of fuel cells can be obtained through in-depth reliability analysis including techniques such as Failure Mode and Effect Analysis (FMEA) and Fault Tree analysis (FTA) amongst others. As hydrogen fuel cells are a relatively new technology this in-depth analysis is still in its infancy, and needs development. This research has extended the work on FTA of the Polymer Electrolyte Membrane Fuel Cell (PEMFC) systems. Detailed analysis has explored the inherent complexity of the PEMFC system where issues with using a basic FTA for a PEMFC, such as dependencies between failure modes, and disparities between failure mode operating principles, are discussed. The integration of the Markov technique, which can deal with dependencies, within the Fault tree approach is suggested as a mechanism to enhance the accuracy of the modelling of a PEMFC
The effects of gas diffusion layers structure on water transportation using X-ray computed tomography based Lattice Boltzmann method
© 2017 Elsevier B.V. The Gas Diffusion Layer (GDL) of a Polymer Electrolyte Membrane Fuel Cell (PEMFC) plays a crucial role in overall cell performance. It is responsible for the dissemination of reactant gasses from the gas supply channels to the reactant sites at the Catalyst Layer (CL), and the adequate removal of product water from reactant sites back to the gas channels. Existing research into water transport in GDLs has been simplified to 2D estimations of GDL structures or use virtual stochastic models. This work uses X-ray computed tomography (XCT) to reconstruct three types of GDL in a model. These models are then analysed via Lattice Boltzmann methods to understand the water transport behaviours under differing contact angles and pressure differences. In this study, the three GDL samples were tested over the contact angles of 60°, 80°, 90°, 100°, 120° and 140° under applied pressure differences of 5 kPa, 10 kPa and 15 kPa. By varying the contact angle and pressure difference, it was found that the transition between stable displacement and capillary fingering is not a gradual process. Hydrophilic contact angles in the region of 60° < θ < 90° showed stable displacement properties, whereas contact angles in the region of 100° < θ < 140° displayed capillary fingering characteristics
X-ray tomography and modelling study on the mechanical behaviour and performance of metal foam flow-fields for polymer electrolyte fuel cells
Porous metal foams have been used as alternative flow-fields in proton exchange membrane fuel cells (PEMFCs), exhibiting improved performance compared to conventional
‘land and channel’ designs. In the current work, the mechanical behaviour of PEMFCs using
metal foam flow-fields is investigated across different length scales using a combination of
electrochemical testing, X-ray computed tomography (CT), compression tests, and finite
element analysis (FEA) numerical modelling.
Fuel cell peak power was seen to improve by 42% when foam compression was
increased from 20% to 70% due to a reduction in the interfacial contact resistance between the foam and GDL. X-ray CT scans at varying compression levels reveal high levels
of interaction between the metal foam and gas diffusion layer (GDL), with foam ligaments
penetrating over 50% of the GDL thickness under 25% cell compression. The interfacial
contact area between the foam and GDL were seen to be 10 times higher than between
the foam and a stainless-steel plate. Modelling results demonstrate highly uniform
contact pressure distribution across the cell due to plastic deformation of the foam. The
effect of stack over-tightening and operating conditions are investigated, demonstrating
only small changes in load distribution when paired with a suitable sealing gasket
material
Characterisation of the diffusion properties of metal foam hybrid flow-fields for fuel cells using optical flow visualisation and x-ray computed tomography
The flow distribution behaviour of open-cell metallic foam fuel cell flow-fields are evaluated using ex-situ optical
analysis and X-ray computed tomography (X-ray CT). Five different manifold designs are evaluated and flow distribution and pressure drop quantitatively evaluated with reference to applications in polymer exchange membrane fuel cells (PEMFC) and heat exchangers. A ‘hybrid’ foam flow-field is presented consisting of flow channels pressed into the foam to promote flow
distribution and reduce pressure drop. Cross- and through-channel pressure drop measurements are conducted, along with X-ray CT analysis. Results using dyed water show that metallic foams provide excellent fluid distribution across the fuel cell
flow-field, closely following the theoretical filling rate. The time for dye to cover 80% of the flow-field area was
61% faster with a foam flow-field then with no flow-field present. Pressure drop was seen to reduce with increasing foam inlet area to levels comparable to multi-serpentine flow-fields. The introduction of flow channels in the foam can further reduce pressure drop and provide more even filling of the foam, at the expense of
increased residence time
Supporting video files: "Characterisation of the diffusion properties of metal foam hybrid flow-fields for fuel cells using optical flow visualisation and X-ray computed tomography"
Underlying experimental data for publication titled 'Characterisation of the diffusion properties of metal foam hybrid flow-fields for fuel cells using optical flow visualisation and X-ray computed tomography'</p
Supplementary data for: "X-ray tomography and modelling study on the mechanical behaviour and performance of metal foam flow-fields for polymer electrolyte fuel cells"
Supplementary data for publication titled "X-ray tomography and modelling study on the mechanical behaviour and performance of metal foam flow-fields for polymer electrolyte fuel cells" published in the International Journal of Hydrogen Energy. https://doi.org/10.1016/j.ijhydene.2019.01.206</p